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Home arrow DIY Plans arrow Alkalinity Calcium arrow Calcium Carbonate Reactor

Calcium Carbonate Reactor PDF Print
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Calcium Carbonate Reactor
Page 2

by Dr_DBW

A calcium carbonate reactor is something that is very easy to build. There is nothing to their design and you can pick and choose a design that suits your DIY abilities. This is my first DIY calcium carbonate reactor and was designed so that it was pretty much just fitting the pieces together and gluing them. No real work involved in having to cut, shape etc the pieces.

This is no longer the reactor that is being used on OZ REEF, it has subsequently been replaced by a more advanced and neat design out of acrylic. Some quite details on that unit will be added at a later date (however it wont be too details since that design is the basis for some commercial units that I now sell). This is still being used somewhere though, I sold it to a fellow member of MASOV (Marine Aquarium Society of Victoria).

The basic design of most calcium carbonate reactors is to have a recirculating column filled with calcium carbonate with a slow water flowrate through the entire unit. The recirculation has some ineffiencies in terms of the amount of carbon dioxide that is required to dissolve the calcium carbonate, but it makes it very easy to make, tune and run. Passing the injected carbon dioxide through the recirculating pump also assists in the dissolution into the water. Below is the diagram of this design that was used.


Diagram of the calcium carbonate reactor.

For this particular construction a large number of simple PVC fittings were used, so that it was just a case of gluing the majority of them together. The only more advanced part was having to drill two holes through the side of the column and one in the lid. The former were for the recirculation loop and the latter for the water outlet. This was achieved by using a hole saw and making the size just under that of the PVC fittings to go through it. Then apply a liberal amount of PVC cememt and slip it through. Worked very well and there was no leakage problems.

The external recirculating pump doesn't have to have a very high flowrate at all and I used an Eheim 1048. Has never missed and beat and is still running 24/7 on the new reactor. It has been going no stop since 1997.

Below is an image of the finished reactor. The vinyl tubing running around makes it a bit untidy and I don't think I would do it like that again, but that was the limit of my ability at that time.


Image of the finished reactor.

Here is the various fittings around the recirculating pump. It all looks a bit messy and all, but it does the job :) On the inlet side of the pump is the water inlet, carbon dioxide inlet and water from the base of the column. Outlet side has the water return back to the aquarium system and the water outlet to the top of the column. Was was drawn from the base of the column as this avoids the pump running dry if there is too much carbon dioxide going into the unit and it fills up.


Close up of the fittings around the recirculating pump.

And finally this is the bubble counter, which is required to be able to monitor the flowrate of carbon dioxide into the reactor. This was made out of an epoxy putty container, with a check valve glued onto either end. Water is sucked in through the bottom to fill it up, then the bottom length of airline is connected to the carbon dioxide source.


Bubble counter.

Carbon Dioxide Supply: Yeast Method

It was the original idea was to use the below as the carbon dioxide supply, and it was used to start with after it was built. But it was found that it was just a little bit too fiddle to keep a good constant pressure. But the good thing is that it can be done, and if you have a bit more time and patience, or lack of money, then I am sure that it can be used for sustained periods of time with no hassle what so ever.


Diagram for the yeast method of supplying carbon dioxide to a calcium carbonate reactor.

Comments
Measurements?
Written by on 2006-04-14 09:00:24
I was looking at the diagram for this reactor and noticed that there were not any measurements for length of the pvc pipes. Can you please tell me what length each pvc pipe needs to be?
Re: Measurements?
Written by Dr DBW on 2006-04-13 09:01:47
It doesn't actually really matter that much. The larger the volume of the column where the calcium carbonate is held, longer time between having to refill it. How quickly things are used up depends on the tank it is being used on. Therefore, the larger your calcium / alkalinity demands, the larger the calcium reactor should be.
Bubble Counter
Written by on 2006-04-14 09:00:44
I dont completely understand how to build the bubble counter. Can you please explain? Also which kind/brand of glue do you use for this project?
Re: Bubble Counter
Written by on 2006-04-14 09:04:34
The bubble counter is just a clear container with airline fittings on the top and bottom. I just happen to have an epoxy putty container lying around, so used that. Doesn't matter what it is, just as long as it isn't too flimsy and can take some pressure. As bit of a short cut, instead of just having an airline fitting on the bottom, I used an airline check valve instead. That means that water will not flow back up the line to the CO2 cylinder. 
 
Glue wise, just use a PVC solvent. I like to use the clear version, which means you can't see it at the joints, plus it actually binds the joints together. The blue version works too and if you make a mistake if you gently warm the joint you can separate it.
Where does the CO2 go?
Written by on 2006-04-27 09:20:07
I follow this diagram perfectly I see the tank water flow in through and out, but what happen to the excess CO2? Dose it end up in the supply line to the tank? And if so, wouldn't that tend to lower overall pH, not to mention exposing us to CO2 every time I open the stand door?
Re: Where does the CO2 go?
Written by on 2006-04-27 09:25:39
Excess CO2 will exit out the same line as the water does. 
 
However, it should not be running with excess CO2. If that is happening then you need to reduce the number of bubbles per minute of CO2 being introduced into the unit. It is a tuning issue. If there is some excess CO2 for a short period of time, it isn't a big issue but it needs to be corrected. 
 
On the safety side, you should not have the CO2 cylinder located in any area where people sleep and preferrably outside. This is because if the unit has a significant leak, the cylinder can introduce a large volume of gas into the air.
CO2 system vs pH value
Written by on 2006-09-13 16:35:36
After reading all the information concerning calcium reactors I have some questions about the low pH value of 6.5 in the reactor chamber to dissolve the media. Does the calcium saturated discharge water from the calcium reactor lower the tank pH.? An Octopus 3000 that controls pH controls my reef tank; I plan to install a 5 gallon per day dosing pump. 
 
What is the best buffer solution used to maintain tank water at pH 8.3 and what system do you suggest? Do I need such a system? 
 
Currently the pH level is about 8.00 during the daytime and drops to 7.89 after the lights go out.
Re: CO2 system vs pH value
Written by on 2006-09-13 16:45:15
Minor note, it is "pH" lower case p followed by uppercase H. 
 
No, the carbon dioxide from the calcium reactor should not decrease the pH of the tank. If it does, then that means you have insufficient gas exchange. And this is going to be caused by poor water movement, poor air movement over the water, or poor air exchange between the room the tank is in and the outside. 
 
There is no need for a "buffer system" if you are using a calcium reactor, since it is adding calcium and alkalinity to your tank. 
 
With the pH value you have there, I would suggest validating that reading, and if it is at around 8.0 still see about improving your gas exchange. I think you will find that it will move up a couple of decimal points if you do.
Number of bubles
Written by on 2007-01-30 09:36:29
How many bubles should you see per min for it to work right or how much co2 should be used? how do you know if you are using enough?
Re: Number of bubbles
Written by on 2007-01-30 09:38:49
That depends entirely on how the particular reactor and operating conditions. As a starting point, I recommend that you start with 60 bubbles per minue of carbon dioxide and 1.5 litres per minute of water. Then you adjust it from there as required. 
 
You know if you are using enough by the pH of the water (plus the alkalniity and calcium concentrations) leaving the calclium reactor. If the pH is not low enough, the insufficient amounts of the substrate will be dissolved and it wont do its job.
Written by on 2007-03-01 12:01:41
I've been dreaming of building one of this calcium reactor but because I'm not really good in putting pieces together I would like to ask if I can buy it from you and how much will it cost me. I'm from NSW Sydney Australia.



 
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